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  1. 4 hours ago · Website. charlestonwv.gov. Charleston is the capital and most populous city of the U.S. state of West Virginia and the county seat of Kanawha County. [7] Located at the confluence of the Elk and Kanawha rivers, the city had a population of 48,864 at the 2020 census and an estimated population of 48,018 in 2021.